A nonmetallic element belonging to group 14 (formerly IVB) of the periodic table; a.n. 6; r.a.m. 12.011; m.p. ~3550°C; b.p. ~4827°C. Carbon has three main allotropic forms (see allotropy).
Diamond (r.d. 3.52) occurs naturally and can be produced synthetically. It is extremely hard and has highly refractive crystals. The hardness of diamond results from the covalent crystal structure, in which each carbon atom is linked by covalent bonds to four others situated at the corners of a tetrahedron. The C–C bond length is 0.154 nm and the bond angle is 109.5°.
Graphite (r.d. 2.25) is a soft black slippery substance (sometimes called black lead or plumbago). It occurs naturally and can also be made by the Acheson process. In graphite the carbon atoms are arranged in layers, in which each carbon atom is surrounded by three others to which it is bound by single or double bonds. The layers are held together by much weaker van der Waals’ forces. The carbon-carbon bond length in the layers is 0.142 nm and the layers are 0.34 nm apart. Graphite is a good conductor of heat and electricity. It has a variety of uses including electrical contacts, high-temperature equipment, and as a solid lubricant. Graphite mixed with clay is the ‘lead’ in pencils (hence its alternative name). The third crystalline allotrope is fullerite (see buckminsterfullerene). There are also several amorphous forms of carbon, such as carbon black and charcoal.
There are two stable isotopes of carbon (proton numbers 12 and 13) and four radioactive ones (10, 11, 14, 15). Carbon–14 is used in carbon dating.
Carbon forms a large number of compounds because of its unique ability to form stable covalent bonds with other carbon atoms and also with hydrogen, oxygen, nitrogen, and sulphur atoms, resulting in the formation of a variety of compounds containing chains and rings of carbon atoms.
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