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单词 Gibbs function
释义
Gibbs function

Geology and Earth Sciences
  • Generally defined in terms of changes in free energy: Δ‎F = Δ‎HTΔ‎S, where H = enthalpy, T = absolute temperature, S = entropy. In a mixture of reactants, if Δ‎F is less than 0 a reaction may take place spontaneously, whereas if Δ‎F is positive energy must be supplied to the system for a reaction to occur at all. In geochemistry, the sign and magnitude of Δ‎F are important. The sign indicates whether a given reaction can occur spontaneously, and the magnitude indicates how far the reaction can go before equilibrium is attained.


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