“Baeyer-Villiger reaction”的概念、定义、翻译、参考文献-科学参考

Baeyer-Villiger reaction

Chemistry

A rearrangement reaction, sometimes known as the Dakin reaction, commonly used in organic synthesis in which a ketone reacts with a peroxy acid to form an ester. For example,
$R - CO - R \to R - CO - O - R$
The reaction is equivalent to the insertion of an oxygen atom next to the ketone’s carbonyl (>C=O) group. Meta-chloroperbenzoic acid (m-CPBA; ClC₆H₄.CO.O.OH) and trifluoroperethanoic acid (CF₃.CO.O.OH) are typical peroxy acids employed in the reaction. It was discovered by Adolf von Baeyer and the German chemist V. Villiger in 1899.

单词	Baeyer-Villiger reaction
释义	Baeyer-Villiger reaction Chemistry A rearrangement reaction, sometimes known as the Dakin reaction, commonly used in organic synthesis in which a ketone reacts with a peroxy acid to form an ester. For example, $R - CO - R \to R - CO - O - R$ The reaction is equivalent to the insertion of an oxygen atom next to the ketone’s carbonyl (>C=O) group. Meta-chloroperbenzoic acid (m-CPBA; ClC₆H₄.CO.O.OH) and trifluoroperethanoic acid (CF₃.CO.O.OH) are typical peroxy acids employed in the reaction. It was discovered by Adolf von Baeyer and the German chemist V. Villiger in 1899.
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