The increase in volume of a substance with temperature. Most substances increase in volume with increasing temperature. The coefficient of expansion, α, is the ratio of the change in length of a substance with temperature to the length at 0ºC. The (p. 376) coefficient of volumetric expansion, β, is approximately three times the value of α. Water is a notable exception in which above 0ºC, the volume decreases with temperature to approximately 4ºC and increases in volume thereafter. The SI unit is K−1.