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单词 Le Chatelier’s principle
释义
Le Chatelier’s principle

Physics
  • If a system is in equilibrium, any change imposed on the system tends to shift the equilibrium to nullify the effect of the applied change. The principle, which is a consequence of the law of conservation of energy, was first stated in 1888 by Henri Le Chatelier (1850–1936). It is applied to chemical equilibria. For example, in the gas reaction

    2SO2+O22SO3

    an increase in pressure on the reaction mixture displaces the equilibrium to the right, since this reduces the total number of molecules present and thus decreases the pressure. The standard enthalpy change for the forward reaction is negative (i.e. the reaction is exothermic). Thus, an increase in temperature displaces the equilibrium to the left since this tends to reduce the temperature. The equilibrium constant thus falls with increasing temperature.


Chemistry
  • If a system is in equilibrium, any change imposed on the system tends to shift the equilibrium to nullify the effect of the applied change. The principle, which is a consequence of the law of conservation of energy, was first stated in 1888 by Henri Le Chatelier (1850–1936). It is applied to chemical equilibria. For example, in the gas reaction

    2SO2+O22SO3

    An increase in pressure on the reaction mixture displaces the equilibrium to the right, since this reduces the total number of molecules present and thus decreases the pressure. The standard enthalpy change for the forward reaction is negative (i.e. the reaction is exothermic). Thus, an increase in temperature displaces the equilibrium to the left since this tends to reduce the temperature. The equilibrium constant thus falls with increasing temperature. Le Chatelier derived his principle using thermodynamics.

    https://web.lemoyne.edu/~giunta/lechat.html Le Chatelier’s original paper


Chemical Engineering
  • A law that states that if a system in physical or chemical equilibrium is subjected to a change in temperature, pressure, or concentration, then the system will automatically alter itself so as to reduce the effects of the change. It can be shown that this law must be true if energy is neither created nor destroyed.


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