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单词 Ostwald’s dilution law
释义
Ostwald’s dilution law

Physics
  • An expression for the degree of dissociation of a weak electrolyte. For example, if a weak acid dissociates in water,

    HAH++A

    the dissociation constant Ka is given by

    Ka=α2n/(1α)V

    where α‎ is the degree of dissociation, n the initial amount of substance (before dissociation), and V the volume. If α‎ is small compared with 1, then α‎2=KV/n; i.e. the degree of dissociation is proportional to the square root of the dilution. The law was first put forward by the German physical chemist F. W. Ostwald to account for electrical conductivities of electrolyte solutions in 1888.


Chemistry
  • An expression for the degree of dissociation of a weak electrolyte. For example, if a weak acid dissociates in water

    HAH++A-.

    The dissociation constant Ka is given by

    Ka=α2n/(1-α)V,

    where α‎ is the degree of dissociation, n the initial amount of substance (before dissociation), and V the volume. If α‎ is small compared with 1, then α‎2 = KV/n; i.e. the degree of dissociation is proportional to the square root of the dilution. The law was first put forward by Wilhelm Ostwald in 1888 to account for electrical conductivities of electrolyte solutions.


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