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单词 covalent radius
释义
covalent radius

Chemistry
  • An effective radius assigned to an atom in a covalent compound. In the case of a simple diatomic molecule, the covalent radius is half the distance between the nuclei. Thus, in Cl2 the internuclear distance is 0.198 nm so the covalent radius is taken to be 0.099 nm. Covalent radii can also be calculated for multiple bonds; for instance, in the case of carbon the values are 0.077 nm for single bonds, 0.0665 nm for double bonds, and 0.0605 nm for triple bonds. The values of different covalent radii can sometimes be added to give internuclear distances. For example, the length of the bond in interhalogens (e.g. ClBr) is nearly equal to the sum of the covalent radii of the halogens involved. This, however, is not always true because of other effects (e.g. ionic contributions to the bonding).


Geology and Earth Sciences
  • The atomic radius of an atom (e.g. carbon), determined in a covalent compound by a technique which can be used only for structures in which that atom (carbon) is covalently bonded. Measurement of the distance between planes of atoms (the ‘d-spacing’) gives the sum of the radii (the bond length) of the two covalently bonded atoms in two planes. If all the atoms in the compound are of the same element this gives the value of the radius of an atom in each plane (e.g. the bond length in diamond (pure carbon) is twice the radius of an individual carbon atom). If atoms of different elements are covalently bonded, the bond length of one of the atoms can be derived from the sum of the two different bond lengths only if the bond length of the other atom is known.


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