请输入您要查询的字词:

 

单词 Wacker process
释义
Wacker process

Chemistry
  • A process for the manufacture of ethanal by the air oxidation of ethene. A mixture of air and ethene is bubbled through a solution containing palladium(II) chloride and copper(II) chloride. The Pd2+ ions form a complex with the ethene in which the ion is bound to the pi electrons in the C=C bond. This decreases the electron density in the bond, making it susceptible to nucleophilic attack by water molecules. The complex formed breaks down to ethanal and palladium metal. The Cu2+ ions oxidize the palladium back to Pd2+, being reduced to Cu+ ions in the process. The air present oxidizes Cu+ back to Cu2+. Thus the copper(II) and palladium(II) ions effectively act as catalysts in the process, which is now the main source of ethanal and, by further oxidation, ethanoic acid. It can also be applied to other alkenes. The process is named after the chemical firm Wacker Chemie, founded by Alexander von Wacker (1846–1922), where research on its development was carried out in the late 1950s.


Chemical Engineering
  • 1. A catalytic process used to oxidize aliphatic hydrocarbons such as ethylene to ethanol, aldehydes, and ketones using oxygen. The process uses an aqueous solution of mixed palladium and copper chlorides either in solution or on a support of activated carbon through which the ethylene is bubbled. The process was invented in 1957 and is named after the chemical company.

    2. A process used for the production of sodium salicylate through the reaction of sodium phenate and carbon dioxide.


随便看

 

科学参考收录了60776条科技类词条,基本涵盖了常见科技类参考文献及英语词汇的翻译,是科学学习和研究的有利工具。

 

Copyright © 2000-2023 Sciref.net All Rights Reserved
京ICP备2021023879号 更新时间:2024/6/30 22:52:59