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单词 variational principle
释义
variational principle

Physics
  • A principle involving the idea that a quantity of interest either be a minimum or a maximum. Many laws of physics are variational principles, examples being Fermat’s principle and the principle of least action.


Chemistry
  • In calculations in quantum mechanics the principle that if a trial wave function is used to calculate the energy of a system, then the energy calculated cannot be lower than the actual energy of the ground state of the system. To use variational principles effectively in quantum mechanics a trial wave function contains parameters that can be varied, with these parameters being changed until the lowest possible energy is found.


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