“Bürgi–Dunitz angle”的概念、定义、翻译、参考文献-科学参考

单词	Bürgi–Dunitz angle
释义	Bürgi–Dunitz angle Chemistry The angle characteristic of a nucleophile when it reacts with a carbonyl group. If the nucleophile is denoted Nu, then the Bürgi–Dunitz angle is the angle Nu – C – O and is usually about 107°. This angle was investigated by Hans-Beat Bürgi and Jack Dunitz in 1974. It can be understood in terms of molecular-orbital theory involving pi bonds (see orbital).
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