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单词 triphenylmethyl
释义
triphenylmethyl

Chemistry
  • An unusual aromatic compound that can exist as an anion, cation or free radical, (C6H5)3C. Treatment of triphenylcarbinol in alcoholic solution with mineral acids produces triphenylmethyl salts, containing the cation (C6H5)3C+, which crystallize as orange-red solids. The action of sodium on a solution of triphenylmethyl chloride in ether produces the yellow (C6H5)3C− anion. The free radical form is made by treating triphenylmethyl chloride with mercury or zinc in the absence of oxygen.


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