请输入您要查询的字词:

 

单词 noble gases
释义
noble gases

Chemistry
  • A group of monatomic gaseous elements forming group 18 (formerly group 0) of the periodic table: helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), and radon (Rn). The electron configuration of helium is 1s2. The configurations of the others terminate in ns2np6 and all inner shells are fully occupied. The elements thus represent the termination of a period and have closed-shell configuration and associated high ionization energies (He 2370 to Rn 1040 kJ mol−1) and lack of chemical reactivity. Being monatomic the noble gases are spherically symmetrical and have very weak interatomic interactions and consequent low enthalpies of vaporization. The behaviour of the lighter members approaches that of an ideal gas at normal temperatures; with the heavier members increasing polarizability and dispersion forces lead to easier liquefaction under pressure. Four types of ‘compound’ have been described for the noble gases but of these only one can be correctly described as compounds in the normal sense. One type consists of such species as HHe+, He2+, Ar2+, HeLi+, which form under highly energetic conditions, such as those in arcs and sparks. They are short-lived and only detected spectroscopically. A second group of materials described as inert-gas–metal compounds do not have defined compositions and are simply noble gases adsorbed onto the surface of dispersed metal. The third type, previously described as ‘hydrates’ are in fact clathrate compounds with the noble gas molecule trapped in a water lattice. True compounds of the noble gases were first described in 1962 and several fluorides, oxyfluorides, fluoroplatinates, and fluoroantimonates of xenon are known. A few krypton fluorides and a radon fluoride are also known although the short half-life of radon and its intense alpha activity restrict the availability of information. Apart from argon, the noble gases are present in the atmosphere at only trace levels. Helium may be found along with natural gas (up to 7%), arising from the radioactive decay of heavier elements (via alpha particles).


Chemical Engineering
  • A group of six monatomic gaseous elements of group 18 in the periodic table that comprise helium, neon, argon, krypton, xenon, and radon. They differ from other gases in that they have a full set of electrons in their outer shell making them very stable. They were once known as inert gases. However, some of the noble gases can take part in chemical reactions. Apart from helium, all are found in trace amounts in the atmosphere.


随便看

 

科学参考收录了60776条科技类词条,基本涵盖了常见科技类参考文献及英语词汇的翻译,是科学学习和研究的有利工具。

 

Copyright © 2000-2023 Sciref.net All Rights Reserved
京ICP备2021023879号 更新时间:2024/6/28 18:33:31