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单词 Wurtz reaction
释义
Wurtz reaction

Chemistry
  • A reaction to prepare alkanes by reacting a haloalkane with sodium:

    2RX+2Na2NaX+RR

    The haloalkane is refluxed with sodium in dry ether. The method is named after the French chemist Charles-Adolphe Wurtz (1817–84), who discovered it in 1855. The analogous reaction using a haloalkane and a haloarene, for example:

    C6H5Cl+CH3Cl+2Na2NaCl+C6H5CH3,

    is called the Fittig reaction after the German chemist Rudolph Fittig (1835–1910), who investigated it in the 1860s.


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