A colourless or pale blue viscous unstable liquid, H2O2; r.d. 1.44; m.p. –0.41°C; b.p. 150.2°C. As with water, there is considerable hydrogen bonding in the liquid, which has a high dielectric constant. It can be made in the laboratory by adding dilute acid to barium peroxide at 0°C. Large quantities are made commercially by electrolysis of KHSO4.H2SO4 solutions. Another industrial process involves catalytic oxidation (using nickel, palladium, or platinum with an anthraquinone) of hydrogen and water in the presence of oxygen. Hydrogen peroxide readily decomposes in light or in the presence of metal ions to give water and oxygen. It is usually supplied in solutions designated by volume strength. For example, 20-volume hydrogen peroxide would yield 20 volumes of oxygen per volume of solution. Although the peroxides are formally salts of H2O2, the compound is essentially neutral. Thus, the acidity constant of the ionization
is 1.5 × 10−12 mol dm−3. It is a strong oxidizing agent, hence its use as a mild antiseptic and as a bleaching agent for cloth, hair, etc. It has also been used as an oxidant in rocket fuels.