“Simmons–Smith reaction”的概念、定义、翻译、参考文献-科学参考

Simmons–Smith reaction

Chemistry

A reaction in which a cyclopropane ring is produced from an alkene. It uses the Simmons–Smith reagent, which was originally diiodomethane (CH₂I₂) with a Zn/Cu couple. Usually, diethyl zinc is used rather than Zn/Cu. The mechanism involves the formation of H₂C(I)(ZnI) and carbene transfer from the zinc to the double bond of the alkene. This reaction is named after Howard Ensign Simmons and Ronald Smith, who discovered it in 1958–59. There has been a considerable amount of work on extensions of the Simmons–Smith reaction.

单词	Simmons–Smith reaction
释义	Simmons–Smith reaction Chemistry A reaction in which a cyclopropane ring is produced from an alkene. It uses the Simmons–Smith reagent, which was originally diiodomethane (CH₂I₂) with a Zn/Cu couple. Usually, diethyl zinc is used rather than Zn/Cu. The mechanism involves the formation of H₂C(I)(ZnI) and carbene transfer from the zinc to the double bond of the alkene. This reaction is named after Howard Ensign Simmons and Ronald Smith, who discovered it in 1958–59. There has been a considerable amount of work on extensions of the Simmons–Smith reaction.
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