“Heilbronner’s rule”的概念、定义、翻译、参考文献-科学参考

Heilbronner’s rule

Chemistry

A rule proposed by the German-Swiss chemist Edgar Heilbronner (1921–2006) in 1964 which states that in cyclic annulenes with Möbius strip conformations the electron counting rule for stability is the opposite to the Hückel rule; in other words, aromaticity for a Möbius strip cyclic annulene occurs when there are 4n pi electrons and anti-aromaticity occurs when there are (4n + 2) pi electrons. There is experimental evidence for the correctness of Heilbronner’s rule.

单词	Heilbronner’s rule
释义	Heilbronner’s rule Chemistry A rule proposed by the German-Swiss chemist Edgar Heilbronner (1921–2006) in 1964 which states that in cyclic annulenes with Möbius strip conformations the electron counting rule for stability is the opposite to the Hückel rule; in other words, aromaticity for a Möbius strip cyclic annulene occurs when there are 4n pi electrons and anti-aromaticity occurs when there are (4n + 2) pi electrons. There is experimental evidence for the correctness of Heilbronner’s rule.
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