“Gibbs–Duhem equation”的概念、定义、翻译、参考文献-科学参考

Gibbs–Duhem equation

Chemistry

An equation describing the relation between the chemical potentials of species in a mixture. If n_i is the amount of species i and μ‎_i is the chemical potential of species i, the Gibbs–Duhem equation states that
$\sum_{i} n_{i} {d μ}_{i} = 0$
This equation implies that the chemical potentials for the species in a mixture do not change independently. Thus, in the case of a binary mixture, if the chemical potential of one species increases, the chemical potential of the other species must decrease. The equation was derived independently by J. W. Gibbs in 1875 and the French physicist Pierre Duhem (1861–1916) in 1886.

单词	Gibbs–Duhem equation
释义	Gibbs–Duhem equation Chemistry An equation describing the relation between the chemical potentials of species in a mixture. If n_i is the amount of species i and μ‎_i is the chemical potential of species i, the Gibbs–Duhem equation states that $\sum_{i} n_{i} {d μ}_{i} = 0$ This equation implies that the chemical potentials for the species in a mixture do not change independently. Thus, in the case of a binary mixture, if the chemical potential of one species increases, the chemical potential of the other species must decrease. The equation was derived independently by J. W. Gibbs in 1875 and the French physicist Pierre Duhem (1861–1916) in 1886.
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