A colourless liquid, H2O; r.d. 1.000 (4°C); m.p. 0.000°C; b.p. 100.000°C. In the gas phase water consists of single H2O molecules in which the H–O–H angle is 105°. The structure of liquid water is still controversial; hydrogen bonding of the type H2O…H–O–H imposes a high degree of structure and current models supported by X-ray scattering studies have short-range ordered regions, which are constantly disintegrating and re-forming. This ordering of the liquid state is sufficient to make the density of water at about 0°C higher than that of the relatively open-structured ice; the maximum density occurs at 3.98°C. This accounts for the well-known phenomenon of ice floating on water and the contraction of water below ice, a fact of enormous biological significance for all aquatic organisms.
Ice has nine distinct structural modifications of which ordinary ice, or ice I, has an open structure built of puckered six-membered rings in which each H2O unit is tetrahedrally surrounded by four other H2O units.
Because of its angular shape the water molecule has a permanent dipole moment and in addition it is strongly hydrogen bonded and has a high dielectric constant. These properties combine to make water a powerful solvent for both polar and ionic compounds. Species in solution are frequently strongly hydrated and in fact ions frequently written as, for example, Cu2+ are essentially [Cu(H2O)6]2+. Crystalline hydrates are also common for inorganic substances; polar organic compounds, particularly those with O–H and N–H bonds, also form hydrates.
Pure liquid water is very weakly dissociated into H3O+ and OH− ions by self ionization:
(see ionic product) and consequently any species that increases the concentration of the positive species, H3O+, is acidic and species increasing the concentration of the negative species, OH−, are basic (see acid). The phenomena of ion transport in water and the division of materials into hydrophilic (water loving) and hydrophobic (water hating) substances are central features of almost all biological chemistry. A further property of water that is of fundamental importance to the whole planet is its strong absorption in the infrared range of the spectrum and its transparency to visible and near ultraviolet radiation. This allows solar radiation to reach the earth during hours of daylight but restricts rapid heat loss at night. Thus atmospheric water prevents violent diurnal oscillations in the earth’s ambient temperature.