A cell in which the chemical energy of a fuel is converted directly into electrical energy. The simplest fuel cell is one in which hydrogen is oxidized to form water over porous sintered nickel electrodes. A supply of gaseous hydrogen is fed to a compartment containing the porous cathode and a supply of oxygen is fed to a compartment containing the porous anode; the electrodes are separated by a third compartment containing a hot alkaline electrolyte, such as potassium hydroxide. The electrodes are porous to enable the gases to react with the electrolyte, with the nickel in the electrodes acting as a catalyst. At the cathode the hydrogen reacts with the hydroxide ions in the electrolyte to form water, with the release of two electrons per hydrogen molecule:
At the anode, the oxygen reacts with the water, taking up electrons, to form hydroxide ions:
The electrons flow from the cathode to the anode through an external circuit as an electric current. The device is a more efficient converter of electric energy than a heat engine, but it is bulky and requires a continuous supply of gaseous fuels. Their use to power electric vehicles is being actively explored.
The second generation of fuel cells uses molten salts, especially carbonates of metals such as lithium and potassium, as electrolytes. The third generation of fuel cells uses conducting solid ionic oxides as electrolytes.