请输入您要查询的字词:

 

单词 electrical double layer
释义
electrical double layer

Chemistry
  • A model of the interface between an electrode and the solution close to it. In this model a sheet of one type of electrical charge surrounds the surface of the electrode and a sheet of the opposite charge surrounds the first sheet in the solution. In the Helmholtz model, put forward by Hermann Helmholtz in 1853, the double layer is regarded as consisting of two planes of charge, with the inner plane of ions from the solution being caused by the charge on the electrode and the outer plane being caused by oppositely charged ions in the solution responding to the first layer of ions. In the Gouy–Chapman model (diffuse double layer) thermal motion of ions is taken into account. Neither model is completely successful since the Helmholtz model exaggerates the rigidity of the structure of the charges and the Gouy–Chapman model underestimates the rigidity of the structure. The Stern model, put forward by Otto Stern (1888–1969) in 1924, improves on both models by assuming that the ions next to the electrode have a rigid structure, while taking the second layer to be as described by the Gouy–Chapman model. More complicated models of the electrical double layer have been proposed.


随便看

 

科学参考收录了60776条科技类词条,基本涵盖了常见科技类参考文献及英语词汇的翻译,是科学学习和研究的有利工具。

 

Copyright © 2000-2023 Sciref.net All Rights Reserved
京ICP备2021023879号 更新时间:2024/9/29 23:02:27