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单词 clay minerals
释义
clay minerals

Chemistry
  • Very small particles, chiefly hydrous silicates of aluminium, sometimes with magnesium and/or iron substituting for all or part of the aluminium, that are the major constituents of clay materials. The particles are essentially crystalline (either platy or fibrous) with a layered structure, but may be amorphous or metalloidal. The clay minerals are responsible for the plastic properties of clay; the particles have the property of being able to hold water. The chief groups of clay minerals are:

    kaolinite, Al4Si4O10(OH)8, the chief constituent of kaolin;

    halloysite, Al4Si4(OH)8O10.4H2O;

    illite, KAl4(Si,Al)8O18.2H2O;

    montmorillonite, (Na,Ca)0.33(Al,Mg)2Si4O10(OH)2.nH2O, formed chiefly through alteration of volcanic ash; and

    vermiculite, (Mg,Fe,Al)3(Al,Si)4O10(OH)2.4H2O, used as an insulating material and potting soil.


Geology and Earth Sciences
  • Members of the phyllosilicates (sheet silicates) with related chemistry, all are hydrous aluminium silicates with layered structure; layers of [SiO4] tetrahedra of composition [Si4O10]4− are joined to Al-O layers (gibbsite-type layers) or (Mg,Fe)-O layers (brucite-type layers). 1:1 sheet silicates have one Si-O layer coupled to one brucite or gibbsite layer and include the serpentine group and the kaolinite or kandite group of clays; 2:1 sheet silicates have two Si-O layers joined to one brucite or gibbsite layer and include the smectite and illite groups of clays, bentonite and montmorillonite, as well as talc and the mica group; 2:2 sheet silicates have two Si-O layers joined to two brucite or gibbsite layers and include the chlorite group. It is difficult to distinguish clay minerals by hand or under the microscope, so sophisticated techniques of X-ray diffraction and scanning electron microscopy (SEM) are used to determine the precise clay mineral under investigation.


Geography
  • A group of hydrous aluminium silicates, such as kaolinite, created by intense rock weathering; see Egli et al. (2002) Clay Minerals 37, 2. Clay minerals affect the structure of soils, as they expand when wet (Barshad (1952) Clays & Clay Min. 1).


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