A process used to reduce the impurities in certain metals, alloys, and semiconductors. It relies on the solubility of an impurity being different in the liquid and solid phases. The process involves a narrow molten zone being progressively moved along (p. 421) the length of a specimen of the material such that the impurities are segregated at one end of the ingot and pure material at the other. Where the impurities have a lower melting point than the material being purified, the impurities travel with the moving zone, and vice versa.
Zone refining was developed by American materials scientist William Gardner Pfann (1917–82) as a method of preparing high-purity materials for the manufacture of transistors. Its early use was for purifying germanium, but it can be extended to any solute–solvent system having an appreciable concentration difference between the solid and liquid phases at equilibrium. It is also known as the float zone process used in semi-conductor materials processing.