An interface between two layers of different materials (as opposed to a homojunction, which is an interface between two differently doped regions of the same semiconductor). There are several different types of heterojunction: metal–metal, metal–semiconductor, semiconductor–semiconductor, and semiconductor–insulator. In the case of semiconductor–semiconductor heterojunctions the gaps between the energy bands of the two semiconductors are different. Heterojunctions are used to construct transistors, known as heterotransistors, and semiconductor lasers.
An example of a semiconductor–insulator heterojunction is the technologically important silicon–silicon oxide junction, which is a key feature of metal–oxide–semiconductor (MOS) devices, with ‘metal’ referring to the metal electrode in such devices.
Heterojunctions can be manufactured using epitaxy. See also heterostructure.