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单词 18-electron rule
释义
18-electron rule

Chemistry
  • A rule used to predict the stability of transition metal complexes, particularly organometallic compounds. It states that stability occurs when the outermost shell of the transition metal atom has 18 electrons. This corresponds to an electron configuration of s2p6d10. The rule was proposed by Irving Langmuir in 1921. As with the octet rule, there are many exceptions.


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