“Nernst–Einstein equation”的概念、定义、翻译、参考文献-科学参考

Nernst–Einstein equation

Chemistry

An equation relating the limiting molar conductivity Λ‎_m⁰ (see Kohlrausch’s law) to the ionic diffusion coefficients, devised by Walter Nernst and Albert Einstein. The Nernst–Einstein equation is
$Λ_{m}^{0} = (F^{2} / R T) (v_{+} z_{+}^{2} D_{+} + v_{-} z_{-}^{2} D_{-}),$
where F is the Faraday constant, R is the gas constant, T is the thermodynamic temperature, v₊ and v_– are the number of cations and anions per formula unit of electrolyte, z₊ and z_– are the valences of the ions, and D₊ and D_– are the diffusion coefficients of the ions. An application of the Nernst–Einstein equation is to calculate the ionic diffusion coefficients from experimental determinations of conductivity.

单词	Nernst–Einstein equation
释义	Nernst–Einstein equation Chemistry An equation relating the limiting molar conductivity Λ‎_m⁰ (see Kohlrausch’s law) to the ionic diffusion coefficients, devised by Walter Nernst and Albert Einstein. The Nernst–Einstein equation is $Λ_{m}^{0} = (F^{2} / R T) (v_{+} z_{+}^{2} D_{+} + v_{-} z_{-}^{2} D_{-}),$ where F is the Faraday constant, R is the gas constant, T is the thermodynamic temperature, v₊ and v_– are the number of cations and anions per formula unit of electrolyte, z₊ and z_– are the valences of the ions, and D₊ and D_– are the diffusion coefficients of the ions. An application of the Nernst–Einstein equation is to calculate the ionic diffusion coefficients from experimental determinations of conductivity.
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