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单词 Gibbs–Helmholtz equation
释义
Gibbs–Helmholtz equation

Chemistry
  • An equation used in thermodynamics to show the temperature dependence of the Gibbs free energy. It has the form:

    (G/T)p=(G-H)/T,

    where G is the Gibbs free energy, H is the enthalpy, T is the thermodynamic temperature, and p is the pressure (which is held constant). The Gibbs-Helmholtz equation can be derived from (∂‎G/∂‎T)p = − S and S = (HG)T using the rules of differentiation. The equation was derived by J. W. Gibbs and H. L. F. von Helmholtz.


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