| 单词 | sigmatropic shift | 
| 释义 | sigmatropic shift [¦sig·mǝ¦träp·ik `shift]  ORGANIC CHEMISTRY A rearrangement reaction that consists of the migration of a sigma bond (that is, the sigma electrons) and the group of atoms that are attached to it from one position in a chain or ring into a new position.  | 
	
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