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高分子链构象统计
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高分子链构象统计
Encyclopedia
理学
高分子链的构象统计
释
conformational statistics of macromolecular chain
高分子链构象统计
用统计力学的方法处理假设的模型链的构象,以计算依赖于构象的各种性质。例如链的均方末端距、转动半径、偶极矩、光学各向异性、光谱二向色性等。分子链可视为统计力学的一个宏观“小体系”,上述性质表征其宏观态,而构象(由链中每个键的内旋转角决定)则代表微观态,其数目称构象数。
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