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谱线混合效应
释义
谱线混合效应
Encyclopedia
理学
大气吸收
释
line mixing effect
谱线混合效应
大多数碰撞展宽的红外振动-转动带都假设观测到的吸收谱是孤立的洛伦兹谱线或福格特(Voigt)谱线,但是,对振动转动谱线形的严格处理应该包含干涉现象,也就是我们说所的谱线混合。谱线混合效应又称为窄化转动碰撞(rotational collisional narrowing)线耦合(line coupling)或Q-branch 坍缩(Q-branch collapse)。比较典型的谱线混合效应见于临近谱线的Q-branch和谱线的远翼上。
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