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聚硅烷
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聚硅烷
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理学
聚硅烷
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polysilane
聚硅烷
以硅原子为主链,有机基团为侧基的一类σ共轭聚合物。其中R1和R2为氢原子、烷基、烃基或芳香基团。其主要合成方法为二氯硅烷与碱金属(钠、钾、锂)脱氯缩合(孚兹偶合)、含氢硅烷均相脱氢偶合、烷氧基二硅烷催化歧化、环硅烷开环聚合及掩蔽二硅烯阴离子开环聚合等。
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