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conical intersection
释义
conical intersection
Encyclopedia
理学
分子物理学
释
conical intersection
角锥交叉
在多原子分子中,两个具有相同对称性与自旋的电子态,其势能曲面在某个几何结构下能量简并,且非绝热耦合效应并不消失的现象。在此处两个电子态的势能面形成圆锥面,又称锥形交叉。
理学
计算与理论化学
释
conical intersection
锥形交叉
具有相同自旋的两个电子态形成的交叉。
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