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碰撞能量转移参数
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碰撞能量转移参数
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碰撞能量转移参数
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collisional energy transfer parameter
碰撞能量转移参数
在非高压极限的条件下,单分子解离反应和双分子的复合反应以及一些复杂的多势阱多通道反应通常具有压力依赖效应,反应速率常数会随着压力变化。其原因是发生反应的分子需要通过与浴气的碰撞使其活化而达到反应的能垒。
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