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电负性均衡原理
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电负性均衡原理
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electronegativity equalization erinciple
电负性均衡原理
R.T.桑德森[注]最早描述了电负性均衡原理。在两个或多个不同原子(或其他组合基团)结合在一起形成分子过程时,体系中各部分的电负性差导致电子从电负性低的区域流向电负性高的区域(即电子从化学势高区流向化学势低区),从而使各组成原子或基团调整电负性而趋于平衡,直至都等于最终分子电负性的原理。
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