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液接电势
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液接电势
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理学
液接电势
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liquid junction potential
液接电势
非热力学平衡电势。当两种不同浓度的电解质溶液相互接触时,由于离子在边界两侧化学势的差异,离子就会从浓度高的一侧迁移至浓度低的一侧。然而,由于阴、阳离子迁移率的差异,就会在两种电解质溶液界面处形成双电层,从而形成液接电势。
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