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沙普尔斯不对称双羟基化反应
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沙普尔斯不对称双羟基化反应
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理学
有机反应
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Sharpless asymmetric dihydroxylation
沙普尔斯不对称双羟基化反应
以K2OsO2(OH)4与二氢奎宁(DHQ)或二氢奎尼丁(DHQD)衍生物形成的手性配合物为催化剂,在铁氰化钾为氧化剂和碳酸钾为添加剂的条件下,烯烃以高产率和高对映选择性转化为光学活性的邻二醇的反应。
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