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抓氢键
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抓氢键
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“抓”氢键
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agostic hydrogen bond
抓氢键
通过过渡金属配体的σ-C—H键作为2电子给体与配位不饱和的中心金属原子的d空轨道配位形成的三中心二电子键。其中氢原子桥连在过渡金属和碳原子(也可以是硅原子或其他主族元素原子)之间,抓氢键中的σ-C可以是烷基、芳基等。
Chemistry
>有机化学>金属有机化学>释义
agostic hydrogen bond
“抓”氢键
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