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扭曲的分子内电荷转移
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扭曲的分子内电荷转移
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扭曲的分子内电荷转移
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twist intra-molecular charge transfer;TICT
扭曲的分子内电荷转移
受激状态下的电子重新排布诱发的构象扭曲现象。某些D-A结构的分子受到激发跃迁到激发态后,电子云重新排布,电荷由电子给体向电子受体转移的同时,会伴随激发态分子构象由平面向扭曲转变。
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