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上/下临界溶液温度
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上/下临界溶液温度
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upper/lower critical solution temperature; UCST/LCST
上/下临界溶液温度
在向下弯的相分离曲线上,临界点的温度就是上临界溶液温度(UCST);在向上弯的相分离曲线上,临界点的温度就是下临界溶液温度(LCST)。如果高分子的分子量是单分散的,相分离曲线的最高点或最低点是临界点(critical point)。当温度高于上临界溶液温度时溶液不会发生相分离。当温度低于下临界溶液温度时溶液不会发生相分离。上临界溶液温度和下临界溶液温度与高分子的分子量有关,也随压力改变。
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