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在一定的宏观条件(温度、压力等)下,若多个系统某个特定的集体激发变得不稳定,该集体激发的现象。在钛酸钡(BaTiO3)一类的位移型铁电体中,某一特定的晶格振动模(通常是频率最低的横光学模)在温度趋于相变点时,其固有频率逐渐减小到零,晶体原子处于新的平衡位置,形成新的结构。
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