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单词
nonequilibrium solvation
释义
nonequilibrium solvation
Encyclopedia
理学
计算与理论化学
释
nonequilibrium solvation
非平衡溶剂化
在溶剂环境下,经过一个溶质电子态跃迁的超快过程(如电子转移或电子态激发),溶质分子的电荷分布迅速发生改变,而溶剂分子的静电极化不能完全跟上溶质电荷密度变化,从而形成一个溶剂极化与溶质电场未达平衡的热力学非平衡态的状态。
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