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对于存在相同键长的分子(例如H2X),其振动和高速转动可以引发局部模式振动,使得分子的对称性降低,分子表现为多振动周期的局部振动,科里奥利(Coriolis)和费米(Fermi)共振相互作用消失或减弱,分子振转能级结构显著变化的理论。
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disposition of drugs
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